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© 2016 CH2M
Delivering Sustainable Solutions to Complex Local Challenges, Worldwide
Tenth International Conference on Remediation of Chlorinated and Recalcitrant Compounds – Battelle 2016
VI at the USEPA Indianapolis Duplex: 
Exploring the Role of Conventional Vapor 
Migration versus a Sewer Preferential 
Pathway 
Chris Lutes, CH2M with Robert Truesdale (RTI)
2Delivering Sustainable Solutions to Complex Local Challenges, Worldwide
© 2016 CH2M
Topics
• Hydrogeology and Henry’s Law Calculations
• Soil Gas Trend vs. Depth
• Attenuation Factors Subslab/Indoor Air
• Advective Driving Force from Deep Soil Gas
• Effect of March 2011 Sealing of First Floor Drain on Dataset
• Helium Tracer Testing
• Potential for Preferential Pathways at Multiple Scales
• Geophysics
3Delivering Sustainable Solutions to Complex Local Challenges, Worldwide
© 2016 CH2M
Water Level (Compare Basement at 6 ft bls)
4Delivering Sustainable Solutions to Complex Local Challenges, Worldwide
© 2016 CH2M
Henry’s Law Analysis 
– Is Source 
Groundwater?
• Reasonable agreement between the
observed deep soil gas PCE
concentrations and those predicted by
Henry’s law
• Chloroform is generally more
concentrated in the deep soil gas than
in groundwater.
• Suggests: (1) PCE is migrating to the
immediate vicinity of the house in
groundwater and vapor intrusion is
driven by transport from groundwater
and (2) chloroform is arriving at the
immediate vicinity of the house at least
in part from other sources, such as a
buried storm sewer or sewer main.
5Delivering Sustainable Solutions to Complex Local Challenges, Worldwide
© 2016 CH2M
Concentration vs. Depth (by Heating Status)
6Delivering Sustainable Solutions to Complex Local Challenges, Worldwide
© 2016 CH2M
Concentrations 
in Individual 
Soil Gas 
Clusters vs. 
Depth Exterior
6
7Delivering Sustainable Solutions to Complex Local Challenges, Worldwide
© 2016 CH2M
Concentrations 
in Individual 
Soil Gas 
Clusters vs. 
Depth Interior
8Delivering Sustainable Solutions to Complex Local Challenges, Worldwide
© 2016 CH2M
Attenuation 
Factors
9Delivering Sustainable Solutions to Complex Local Challenges, Worldwide
© 2016 CH2M
Plenty of Potential Entry Points
10Delivering Sustainable Solutions to Complex Local Challenges, Worldwide
© 2016 CH2M
Deep to Shallow Differential Pressure – Advective Driving 
Force (mitigation on and off cycles)
11Delivering Sustainable Solutions to Complex Local Challenges, Worldwide
© 2016 CH2M
Deep to Shallow Differential Pressure – Advective Driving 
Force (box fan on and off cycles)
12Delivering Sustainable Solutions to Complex Local Challenges, Worldwide
© 2016 CH2M
Chloroform Data Shows a Correlation to Heating Degree 
Days except for Points Before March 2011 Drain Sealing
13Delivering Sustainable Solutions to Complex Local Challenges, Worldwide
© 2016 CH2M
Temporal 
Variability ‐
Chloroform
0.01
0.1
1
10
100
01‐Jan‐11
02‐Jul‐11
01‐Jan‐12
02‐Jul‐12
01‐Jan‐13
02‐Jul‐13
01‐Jan‐14
03‐Jul‐14
Concentration (µg/m3)
Date
Indoor Air Chloroform (Passive Sampler Data)
422 First Chloroform
422 Base S Chloroform
420 Base S Chloroform
Ambient Chloroform
Mitigation On
Mitigation Passive
14Delivering Sustainable Solutions to Complex Local Challenges, Worldwide
© 2016 CH2M
Temporal 
Trend: 
PCE
0.01
0.1
1
10
100
01‐Jan‐11
02‐Jul‐11
01‐Jan‐12
02‐Jul‐12
01‐Jan‐13
02‐Jul‐13
01‐Jan‐14
03‐Jul‐14
Concentration (µg/m3)
Date
Indoor Air PCE (Passive Sampler Data)
422 First PCE
422 Base S PCE
420 Base S PCE
Ambient PCE
Mitigation On
Mitigation Passive
Mitigation On
Mitigation Passive
15Delivering Sustainable Solutions to Complex Local Challenges, Worldwide
© 2016 CH2M
Tracer Test Procedures
• Helium injected to 13 ft exterior soil gas location, deepest depth normally above
water table
• 18 to 26 liter injections
• Tests 1 & 2 injection in front yard tests3 & 4 injection in the back yard
• The mitigation system was on during tests 2 and 4
15
16Delivering Sustainable Solutions to Complex Local Challenges, Worldwide
© 2016 CH2M
Tracer Tests Conclusions
• The variability between paired tests (mitigation on and mitigation off) was more pronounced
beneath the building where the mitigation system would be expected to have the most
significant influence on airflow.
• The highest concentrations observed were usually those close to the 13-ft deep injection depth,
suggesting attenuation as the tracer migrated upward.
• The high concentrations observed at the 9-ft and 13-ft depths for all the injections, despite the
buoyancy of the helium-enriched soil gas, suggest that transference of helium is easy
horizontally toward the building over distances of up to 20 ft typically within 2 days.
• Vertical migration from 13 ft to 6 ft bls also occurred relatively rapidly at the injection cluster.
• In all cases, tracer concentrations were reduced to baseline concentrations within 2–2.5 days,
indicating a rather quick clearing out of trace gas from the subsurface under mitigated and non-
mitigated conditions.
17Delivering Sustainable Solutions to Complex Local Challenges, Worldwide
© 2016 CH2M
Mapping Potential Preferential 
Pathway at Multiple Scales 
18Delivering Sustainable Solutions to Complex Local Challenges, Worldwide
© 2016 CH2M
Geophysics Observations
• 422 basement, 500
MHz GPR South to
North
• Shows evidence of
filled cistern and
doorway
Doorwa
y
Cistern
19Delivering Sustainable Solutions to Complex Local Challenges, Worldwide
© 2016 CH2M
Geophysics 
Observations
• 422Basement 900 MHz GPR South
North
• Shows evidence of depth of sewer
line under slab
• Interior GPR suggests the concrete
slab varies from 0.5 to 0.7 feet with
undulating contact with underlying
materials
• Suggests concrete not poured on
flattened fill
20Delivering Sustainable Solutions to Complex Local Challenges, Worldwide
© 2016 CH2M
Summary
• Henry’s law analysis suggests deep soil gas and groundwater agree for PCE, not so well for
chloroform
• Pattern of PCE different at exterior and interior soil gas clusters;
• Subslab to indoor attenuation factors in line with expectations for building of this age
• Subslab to indoor air attenuation factors similar for PCE, chloroform and radon
• Advective driving force present from deep to subbasement soil gas
• Chloroform on first floor clearly influenced by floor drain before sealing in March 2011
• Sealing efforts did not effect PCE trend in indoor air
• Tracer test shows rapid movement from deep soil gas to subslab
• Potential preferential pathway influences should be evaluated at multiple scales – neighborhood, lot
and building envelope
• Geophysics mapped sewer line and cistern
20
21Delivering Sustainable Solutions to Complex Local Challenges, Worldwide
© 2016 CH2M
Acknowledgements and Information Sources
Data discussed today was collected with EPA NERL Funding – Brian Schumacher and John
Zimmerman, PIs.
Today’s discussions of the data set have not been EPA reviewed. EPA reviewed reports are
available for more information:
 First: “Fluctuation Of Indoor Radon And VOC Concentrations Due To Seasonal Variations”
http://nepis.epa.gov/Exe/ZyPURL.cgi?Dockey=P100KK1J.txt
 Second: “Assessment of Mitigation Systems on Vapor Intrusion: Temporal Trends, Attenuation
Factors, and Contaminant Migration Routes under Mitigated and Non-mitigated Conditions”
http://cfpub.epa.gov/si/si_public_record_report.cfm?dirEntryId=308904
• Third: “Simple, Efficient, and Rapid Methods to Determine the Potential for Vapor Intrusion into the
Home: Temporal Trends, Vapor Intrusion Forecasting, Sampling Strategies, and Contaminant
Migration Routes” http://cfpub.epa.gov/si/si_public_record_report.cfm?dirEntryId=309644
• And a Fourth as a Journal Article: Lutes, C. C., Truesdale, R. S., Cosky, B. W., Zimmerman, J. H.,
& Schumacher, B. A. (2015). Comparing Vapor Intrusion Mitigation System Performance for VOCs
and Radon. Remediation Journal, 25(4), 7-26.

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