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Eigen functions and Eigenvalues -Postulates of
quantum mechanics Time Schrödinger wave
equation - Application to particle in a one
dimensional box – Normalization of wave functions
- Application of Schrödinger wave equation to
hydrogen atom – Conversion of cartesian
coordinates to polar coordinates - Radial and
angular functions (mention only) – Orbitals and
concept of Quantum numbers
Energy levels in molecules - Born-
Oppenheimer approximation. Rotational,
vibrational, Raman, Electronic and NMR
spectroscopy: Basic Principles and
applications. Elements of symmetry of
molecules
Amorphous and crystalline solids , Defects in
crystals - Stoichiometric and non stoichiometric
defects .
Ideal and non ideal solutions -Henry's law ,
Raoult's law - Dilute solutions - Colligative
properties - Abnormal molecular mass – Van’t Hoff
factor.
Solubility product and common ion effect,
precipitation of cations , Principles of
volumetric analysis, Theories of indicators.
Principles and applications of Column
chromatography, Paper chromatography,
Thin layer chromatography, Ion exchange
chromatography, - Rf values.
Structure and applications of silicones, silicates
and zeolites. Cement , Glass , Inorganic
fertilizers , Rocket propellants (Brief study)
Types of pollution: Air and water. Pollutants ,
Control of air and water pollution
Atom Models– Planck’s quantum Theory -
Photoelectric effect -de Broglie's relation – Dual
nature of matter and radiation, Heisenberg's
uncertainty principle. Atomic orbitals and Quantum
numbers - Pauling’s Exclusion principle - Hund’s rule
of maximum multiplicity - Aufbau’s principle –
Electronic configuration of atoms.
Ionic bond – Properties - Born-Lande equation (derivation
not expected) – Born-Haber cycle– Fajan's rules and its
applications. Covalent bond - Valence bond theory–VSEPR
Theory -Concept of Hybridisation –-Types: sp,
sp2,sp3,dsp2,sp3d,d2sp3 ,sp3d2- Explanation with simple
examples .Molecular Orbital Theory – LCAO - Bonding and
antibonding molecular orbitals - Bond order. Theories of
Metallic bonding: Free electron theory, valence bond
theory and band theory (Basics concepts only).Hydrogen
bond – Intra and intermolecular hydrogen bond.
Periodic laws, – Periodic properties – Electronegativity
scales (Pauling and Mullikan scales) – Effective nuclear
charge – Slater rule – Diagonal relationship
Representative and Transition Elements – General
Characteristics, preparation and properties of simple
compounds. Lanthanides and actinides
Metals: Occurrence, Concentration of ores,
Refining of metals, Extractive metallurgy of Al, Fe,
Ni, Cu and Ti – Classification of steel, hardening of
steel.
Isomerism in coordination compounds - Werner’s
theory -EAN rule - Valence bond theory - Crystal
field theory - Splitting of d-orbitals in octahedral,
tetrahedral and square planar complexes –
Applications
Organometallic Compounds: Definition, Classification
and Applications
Radioactivity –Natural and artificial, Nuclear stability –
N/P ratio –Nuclear forces –Half life period – Gieger
Nuttal rule –Disintegration series – Transmutation ,
Nuclear fission and Nuclear fusion –Application of
radioactive isotopes
Postulates of kinetic theory of gases - Collision
number.
First law of thermodynamics – Joule-Thomson effect -
Liquefaction of gases – Inversion temperature. Second
law of thermodynamics - Concept of entropy - Entropy
as criteria of spontaneity. Free energy functions -
Hess’s law, Bond energies. Third law of
thermodynamics.
Law of mass action - Law of chemical equilibrium -
Equilibrium constant in terms of concentration,
partial pressure and mole fractions Van't Hoff’s
equation - Homogeneous and heterogeneous
equilibria - Le Chatelier’s Principle and its
applications.
Rate of a reaction - Factors influencing the rate of a
reaction - Rate law - Order and molecularity - Rate
constants for first, second, third and zero order
reactions - half life period for first order reaction-
Arrhenius equation - Collision theory - Transition
state theory - Homogeneous and heterogenous
catalysis - Enzyme catalysis
Photosynthesis - Simple Photochemical reactions –
Fluorescence – Phosphorescence Chemisorption
and physisorption - Factors affecting adsorption -
Adsorption isotherms Classification , Preparation,
purification and properties of colloids, Protective
colloids - Gold number - Applications of colloids.
Phase Equilibria: Components and degrees of
freedom - One component and two component
systems (Simple cases only)
Faraday's laws, Kohlrausch’s law - Arrhenius theory,
Ostwald’s dilution law – Debye - Huckel - Onsager's
equations for strong electrolytes, Galvanic cells,
electrochemical series - Nernst equation
Uniqueness of Carbon , Classification of organic
compounds - Hybridization of carbon in organic
compounds. Structural and Stereoisomerism, Baeyer
strain theory, Conformation and configuration - Specific
rotation – Chirality, Enantiomers, Diastereomers–
Racemic mixture - Resolution methods
Inductive effect, Mesomeric effect,
Hyperconjugation and Electromeric effect -
Steric effect. organic reactions: Substitution,
Addition, Elimination and Rearrangement .
Mechanisms of SN1, SN2, E1 & E2
Nomenclature of organic compounds– Preparation and
properties of alkanes, alkenes, alkynes, alkyl halides,
alcohols, aldehydes and ketones, carboxylic acids &
their derivatives.
Aromaticity, Huckel's rule - Structure and stability of
benzene, Electrophilic substitution reactions in benzene
with mechanisms
Grignard reagent-Preparation and synthetic applications
Classification of polymers, preparation and
applications of important polymers, biodegradable
polymers
Biomolecules: Carbohydrates, proteins, nucleic
acids, vitamins (Classifications with examples,
applications/functions)
Hsa phy syll detail.pptx
Hsa phy syll detail.pptx

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Hsa phy syll detail.pptx

  • 1.
  • 2. Eigen functions and Eigenvalues -Postulates of quantum mechanics Time Schrödinger wave equation - Application to particle in a one dimensional box – Normalization of wave functions - Application of Schrödinger wave equation to hydrogen atom – Conversion of cartesian coordinates to polar coordinates - Radial and angular functions (mention only) – Orbitals and concept of Quantum numbers
  • 3. Energy levels in molecules - Born- Oppenheimer approximation. Rotational, vibrational, Raman, Electronic and NMR spectroscopy: Basic Principles and applications. Elements of symmetry of molecules
  • 4. Amorphous and crystalline solids , Defects in crystals - Stoichiometric and non stoichiometric defects . Ideal and non ideal solutions -Henry's law , Raoult's law - Dilute solutions - Colligative properties - Abnormal molecular mass – Van’t Hoff factor.
  • 5. Solubility product and common ion effect, precipitation of cations , Principles of volumetric analysis, Theories of indicators.
  • 6. Principles and applications of Column chromatography, Paper chromatography, Thin layer chromatography, Ion exchange chromatography, - Rf values.
  • 7. Structure and applications of silicones, silicates and zeolites. Cement , Glass , Inorganic fertilizers , Rocket propellants (Brief study) Types of pollution: Air and water. Pollutants , Control of air and water pollution
  • 8. Atom Models– Planck’s quantum Theory - Photoelectric effect -de Broglie's relation – Dual nature of matter and radiation, Heisenberg's uncertainty principle. Atomic orbitals and Quantum numbers - Pauling’s Exclusion principle - Hund’s rule of maximum multiplicity - Aufbau’s principle – Electronic configuration of atoms.
  • 9. Ionic bond – Properties - Born-Lande equation (derivation not expected) – Born-Haber cycle– Fajan's rules and its applications. Covalent bond - Valence bond theory–VSEPR Theory -Concept of Hybridisation –-Types: sp, sp2,sp3,dsp2,sp3d,d2sp3 ,sp3d2- Explanation with simple examples .Molecular Orbital Theory – LCAO - Bonding and antibonding molecular orbitals - Bond order. Theories of Metallic bonding: Free electron theory, valence bond theory and band theory (Basics concepts only).Hydrogen bond – Intra and intermolecular hydrogen bond.
  • 10. Periodic laws, – Periodic properties – Electronegativity scales (Pauling and Mullikan scales) – Effective nuclear charge – Slater rule – Diagonal relationship Representative and Transition Elements – General Characteristics, preparation and properties of simple compounds. Lanthanides and actinides
  • 11. Metals: Occurrence, Concentration of ores, Refining of metals, Extractive metallurgy of Al, Fe, Ni, Cu and Ti – Classification of steel, hardening of steel. Isomerism in coordination compounds - Werner’s theory -EAN rule - Valence bond theory - Crystal field theory - Splitting of d-orbitals in octahedral, tetrahedral and square planar complexes – Applications
  • 12. Organometallic Compounds: Definition, Classification and Applications Radioactivity –Natural and artificial, Nuclear stability – N/P ratio –Nuclear forces –Half life period – Gieger Nuttal rule –Disintegration series – Transmutation , Nuclear fission and Nuclear fusion –Application of radioactive isotopes
  • 13. Postulates of kinetic theory of gases - Collision number. First law of thermodynamics – Joule-Thomson effect - Liquefaction of gases – Inversion temperature. Second law of thermodynamics - Concept of entropy - Entropy as criteria of spontaneity. Free energy functions - Hess’s law, Bond energies. Third law of thermodynamics.
  • 14. Law of mass action - Law of chemical equilibrium - Equilibrium constant in terms of concentration, partial pressure and mole fractions Van't Hoff’s equation - Homogeneous and heterogeneous equilibria - Le Chatelier’s Principle and its applications.
  • 15. Rate of a reaction - Factors influencing the rate of a reaction - Rate law - Order and molecularity - Rate constants for first, second, third and zero order reactions - half life period for first order reaction- Arrhenius equation - Collision theory - Transition state theory - Homogeneous and heterogenous catalysis - Enzyme catalysis
  • 16. Photosynthesis - Simple Photochemical reactions – Fluorescence – Phosphorescence Chemisorption and physisorption - Factors affecting adsorption - Adsorption isotherms Classification , Preparation, purification and properties of colloids, Protective colloids - Gold number - Applications of colloids.
  • 17. Phase Equilibria: Components and degrees of freedom - One component and two component systems (Simple cases only) Faraday's laws, Kohlrausch’s law - Arrhenius theory, Ostwald’s dilution law – Debye - Huckel - Onsager's equations for strong electrolytes, Galvanic cells, electrochemical series - Nernst equation
  • 18. Uniqueness of Carbon , Classification of organic compounds - Hybridization of carbon in organic compounds. Structural and Stereoisomerism, Baeyer strain theory, Conformation and configuration - Specific rotation – Chirality, Enantiomers, Diastereomers– Racemic mixture - Resolution methods
  • 19. Inductive effect, Mesomeric effect, Hyperconjugation and Electromeric effect - Steric effect. organic reactions: Substitution, Addition, Elimination and Rearrangement . Mechanisms of SN1, SN2, E1 & E2
  • 20. Nomenclature of organic compounds– Preparation and properties of alkanes, alkenes, alkynes, alkyl halides, alcohols, aldehydes and ketones, carboxylic acids & their derivatives. Aromaticity, Huckel's rule - Structure and stability of benzene, Electrophilic substitution reactions in benzene with mechanisms Grignard reagent-Preparation and synthetic applications
  • 21. Classification of polymers, preparation and applications of important polymers, biodegradable polymers Biomolecules: Carbohydrates, proteins, nucleic acids, vitamins (Classifications with examples, applications/functions)