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DENTAL WAXES
PRESENTED BY,
EAKETHA LOKESH
PG 2nd YEAR
CONTENTS
1. Introduction
2. Historical background
3. Classification
4. Individual component waxes
5. General composition of dental waxes
6. Ideal requisites of dental waxes
7. Properties of waxes
8. Different types of dental waxes
9. Summary
10. References
2
INTRODUCTION
• Variety of natural waxes and resins have been used in
dentistry for specific and well defined applications
• Few procedures in Prosthodontics can be completed
without the use of wax in one of its many forms.
• It is obvious that the tasks these waxes perform and
their properties vary greatly.
3
A low-molecular-weight hydrocarbons or ester of fatty
acids derived from natural or synthetic components,
such as petroleum derivatives, that soften to a plastic
state at a relatively low temperature.
4
Natural and synthetic waxes
Gums
Fats
Fatty acids
Oils
Natural and
synthetic resins
Pigments of
different types.
5
DEFINITION
Dental waxes can be defined as a
thermoplastic molding material that
is solid at room temperature and
when subjected to moderate
temperatures becomes a low
viscosity fluid. Waxes are
hydrocarbons or alcohols or esters
of fatty acids.
6
•Color coding: blue, green, yellow, red and
ivory
•These colors are useful to provide a suitable
contrast against a die that is an accurate
replica of a prepared tooth or arch form.
7
HISTORICAL BACKGROUND
• Wax has been a valuable commodity for over 2000
years.
• In ancient times beeswax was used ,which was derived
from secretions that bees use to build honeycombs.
8
• First inlay in dentistry is credited to JOHN MURPHY of
London who was fabricating porcelain inlay in 1855.
• First cast inlay is attributed to PHILBROOK in 1897.
• TAGGART in 1907 introduced lost wax technique
9
CLASSIFICATION OF
WAXES
10
CLINICAL LABORATORY
 Bite registration
wax
 Disclosing wax
 Type I inlay wax
 Boxing wax
 Beading wax
 Baseplate wax
 Sticky wax
 Utility wax
 Type II Inlay wax
11
12
Based on components of dental
waxes
Natural waxes
Synthetic waxes
Wax additives
•Based on origin of waxes can be classified as
– Natural : mineral origin
plant origin
insect origin
animal origin
– Synthetic waxes
13
TYPE OF WAX APPLICATION
Pattern wax Inlay wax
Resin wax
Casting wax
Baseplate wax
Impression wax Corrective wax
Biteplate wax
Soft impression wax
Disclosing wax
Processing wax Boxing wax
Beading wax
Sticky wax
Carding and blockout wax
Utility waxes 14
Based on uses
•Based on chemical composition
Waxes containing organic compounds
Hydrocarbons
Esters
Waxes containing free alcohols and acids
15
INDIVIDUAL
COMPONENTS
OFWAXES
16
17
• Coloring agents are added for contrast of wax
patterns against tooth, die, and model surfaces.
• Some formulations contain a compatible filler to
control expansion and shrinkage of the wax product.
18
19
COMPONENTS OF DENTAL WAXES
NATURAL
WAXES
SYNTHETIC
WAXES
ADDITIVES
 MINERAL
 PLANT
 INSECT
 ANIMAL
 POLYETHYLENE
 POLYOXYETHELENE
 HYDROGENATED
 OILS
 COLORS
 FATS
 NATURAL
RESINS
 SYNTHETIC
RESINS
20
NATURAL SYNTHETIC
WAXES
ADDITIVES
MINERALS Paraffin
Microcrystalline
Barnsdahl
Ozokerite
Ceresin
Montan
Acrawax C
Aerosol OT
Castor wax
Flexowax C
Epolene N-10
Albacer
Aldo 33
Durawax 1032
Fats
• Stearic acid
• Glyceryl
tristeartae
Oils
• Turpentine
• color
PLANTS Carnuaba
Ouricury
Candelilla
Japan wax
Coco butter
Natural resins
Rosin
Copal
Dammar
Sandarac
Mastic
Shellac
Kauri
INSECTS
ANIMALS
Beeswax
spemaceti
Synthetic resins
Elvax
Polyethylene
NATURAL
WAXES
21
i. Paraffin wax:
Major component of most dental waxes.
Obtained from the high boiling point fractions
of petroleum.
The presence of oil in the wax however lowers
the melting temperature.
22
MINERAL ORIGIN
paraffin waxes used in dentistry are refined
waxes and have less than 5% oil.
They melt at in the range of 400C and 710C.
Melting temperature increases with
increasing molecular weight.
23
Paraffin waxes produced by current refining
procedures that can crystallize in the form of
plates, needles and small crystals
 but are usually of plate type.
Many hydrocarbon waxes undergo crystalline
changes on cooling
 transition from needles to plates occurs about 50
to 80C below their melting temperature
24
 Paraffin wax flakes easily when trimmed and
does not achieve a smooth and glossy surface.
 Hence other waxes and resins have to be
added to modify paraffin and improve
properties of dental waxes.
25
Are similar to paraffin waxes except they are
obtained from the heavier oil fractions in the
petroleum industry.
They consist of mixture of microcrystalline
hydrocarbons, which is purified branched chain of
hydrocarbons, saturated monocyclic and polycyclic
compounds and normal alkanes.
They have higher melting range (600C to 910C)
26
ii. Microcrystalline wax:
crystallize in small plates
tougher
more flexible than paraffin waxes.
They are darker in color and have higher viscosity.
They have an affinity for oil
hardness and tackiness may be altered by adding
oil.
27
Microcrystalline waxes have less volumetric
change during solidification than paraffin waxes.
These waxes are added to paraffin wax to
To raise melting point and hardness
Make material less brittle
They reduces stresses that occur on cooling
28
It is an earth wax found near petroleum deposits
in Central Europe and the Western United States.
It is composed of straight and branched chain
hydrocarbons, along with few closed-chain
hydrocarbons.
29
iii. Ozokerite
Greatest affinity for oils, and in quantities of 5% to
15% greatly improves the properties of paraffin
wax.
Unpleasant odour
Melting point 65o C
30
White wax extracted from ozokerite
Composed of straight and branched chain
hydrocarbons.
higher molecular weight and greater hardness
than hydrocarbon waxes distilled from crude
products.
used to increase the melting range of paraffin
waxes.
31
iv. Ceresin:
Hard wax obtained by solvent extraction of certain
types of lignite or brown coal.
Although they are mineral waxes, their
composition and properties are similar to
those of the plant waxes.
32
v. Montan wax
Composed of long chain esters.
Melting range- 720 C- 920 C
Hard, brittle and lustrous
they blend well with other waxes, and therefore
are often substituted for plant waxes to improve
the hardness and melting range of paraffin waxes.
33
PLANT ORIGIN
i. Carnauba wax and Ouricury wax:
Both composed of straight chain esters, alcohols
and hydrocarbons.
Characterized by high hardness, brittleness and
high melting temperatures
34
Both possess the outstanding quality of increasing
the melting range and hardness of paraffin waxes.
Adding 6% of carnauba wax to paraffin wax with a
melting range of 200C, increases the melting range
to 460C.
35
Consists of 40 to 60% paraffin hydrocarbons
containing 29 to 33 carbon atoms, accompanied by
free alcohols, acids esters and lactones.
Melting range is lower than carnauba wax( 63-
700c)
Like carnauba and ouricury wax, they harden
paraffin waxes but are not so effective for
increasing melting range
Craig et al. Properties of natural waxes used in dentistry. J.Dent. Res.Nov-
Dec 1965
36
ii. Candelilla wax
Chiefly fat
Obtained from berries of certain sumac
Glycerides of palmitic acid and stearic acid
Tough, malleable and sticky
Melting point: 51oc
Mixed with paraffin to improve tackiness and
emulsifying ability
Craig et al. Properties of natural waxes used in dentistry. J.Dent.
Res.Nov-Dec 1965 37
iii. Japan wax (Sumac wax)
Chiefly fat
Composed of glycerides of stearic acid, palmitic,
oleic, lauric, lower fatty acids
Brittle at room temperature
38
iv. Coco butter
• Used to protect against dehydration of soft tissues
• To protect GIC from moisture or dehydration during
their setting.
39
INSECT ORIGIN
Obtained from honey combs
desirable flow properties
Is a brittle material at room temperature
becomes plastic when heated.
Craig et al. Properties of natural waxes used in dentistry. J.Dent.
Res.Nov-Dec 1965 40
Beeswax
 Melting temp range : 63-70oc
 Mixture of saturated and unsaturated
hydrocarbons, organic acids and myricyl palmitate
 Main component of sticky wax
41
ANIMAL ORIGIN
Obtained from the sperm whale
 Mainly esters
 Not used extensively in dentistry
 Some times used for coating the dental
floss
42
Spermaceti wax
SYNTHETIC
WAXES
43
Synthetic waxes are produced by
 combination of various chemicals in the
laboratory
 chemical action on natural waxes
Such as chlorine in the preparation of halogenated
waxes and hydrogen in the manufacture of
hydrogenated waxes
44
• Differ from natural waxes in certain characteristics
high degree of refinement, in contrast with the
contamination that is common in natural waxes.
45
Synthetic waxes include
• Polyethylene waxes
• polyoxyethylene glycol waxes
• Halogenated hydrocarbon waxes
• Wax esters from reaction of fatty alcohol and acids
46
WAX
ADDITIVES
47
I. GUMS
Viscous, amorphous exudates that harden on
exposure to air
largely carbohydrates.
when they are mixed with water, they either
dissolve or form sticky, viscous liquids.
48
• GUM ARABIC and TRAGACANTH are two natural
gums (do not resemble waxes in either their
properties or composition)
49
II. FATS
Esters of various fatty acids
Tasteless, odorless and colorless (pure form)
Increase the melting range and hardness of the
compounded wax
Craig et al. Properties of natural waxes used in dentistry. J.Dent.
Res.Nov-Dec 1965 50
Hydrocarbon oils may be used to soften mixtures
of waxes
Small quantities of silicon oils may be added to
improve the ease of polishing with waxes.
51
III. RESINS
52
NATURAL RESINS SYNTHETIC RESINS
Dammar polyethylene
Rosin vinyl resin
Sandarac polystyrene
Shellac
Copal
• Complex, amorphous mixtures of organic substances
• Characterized by specific physical behavior rather
than by any definite chemical composition.
• Many species of trees and other plants produce
exudates of natural resins such as dammar, rosin or
sandarac ,
• Except shellac which is produced by insects.
53
• Most of the natural resins like dammar blend with
waxes to get the desirable properties for dental
applications.
• Synthetic resins, such as polyethylene and vinyl resins
of various types may be added to paraffin waxes to
improve their toughness, film forming characteristics
and melting ranges.
54
GENERAL
COMPOSITION OF
DENTAL WAXES
55
COMPONENT INGREDIENT EXAMPLE
Base Paraffin
Modifiers High molecular
weight
hydrocarbon or
ester
Beeswax
Carnauba wax
Candelilla wax
Ceresin
colorants
56
IDEAL
REQUISITES OF
DENTAL
WAXES
57
 Should flow easily
 Should be dimensionally stable
 Should have a pleasant colour
and should possess a colour
contrast to help during carving
and proper finishing of
margins.
 When softened, the wax
should be uniform
58
 Should be tough and rigid at
room temperature and not
brittle.
 Should have a low softening
temperature
 It should have a low
coefficient of thermal
expansion
 Should reproduce finer
59
 It should not leave any
residues when wax is
eliminated from the mould
 Should be cheap and easy to
use.
 Should be sufficiently strong
to resist abrasion and
distortion.
PROPERTIES
OF WAXES
60
Thermal properties
Mechanical properties
Flow/ rheological properties
Residual stress
Burnout
61
THERMAL
PROPERTIES
Melting point/ range
Softening temperature
Thermal conductivity
The coefficient of thermal expansion
62
I. MELTING RANGE
63
• Because waxes are mixtures of different components,
they donot have a single temperature
• Donot have a melting points
• Rather they have “ MELTING RANGE”
• At a low end of the range, some but not all
components melt, which causes the wax, still solid , to
flow much more.
• As the temperature ↑ ses through the melting range,
more of the components melt and the wax flow
severely & eventually all components become liquid.
• Significance: mixing of waxes can change their
melting range.
64
II. SOFTENING TEMPERATURE
Waxes exhibit solid-solid transition temperature ,
which is closely related to the softening
temperature.
65
66
Typical thermograph of wax indicating solid-
solid transition (a) and melting point (b)
• This peak is indicative of a solid-solid transition
involving a change in the crystal structure of the wax.
• The change in the crystal structure is accompanied by
a change in the in the mechanical properties and the
wax is converted from a relatively brittle solid to a
much softer, moldable material.
• For this reason the solid-solid temperature is referred
to as softening temperature.
67
 Clinical significance:
 For many applications of waxes, the softening
temperature should be just above the mouth
temperature.
the material may be introduced into the mouth in a
moldable state
but will become relatively rigid at mouth temperature.
68
III. CO-EFFICIENT OF THERMAL
EXPANSION
• Major factor affecting the accuracy.
• Waxes expand when subjected to a rise in
temperature and contract as the temperature is
decreased .
69
• Dental waxes and their components have the largest
co-efficient of thermal expansion of any material used
in restorative dentistry.
• Very large coefficient of thermal expansion –150-
400ppm /0 C
• Due to this large COTE, contraction of wax patterns
take place by about 0.3% to 0.8% when cooled from
370c to room temperature
70
IV. THERMAL CONDUCTIVITY
Waxes are poor conductors of heat
Thus temperature should be maintained above the
solid-solid transition temperature for long enough
to allow thorough softening to occur throughout
the material before molding is attempted
The practical implication is heat slowly and
uniformly.
71
The different methods of softening wax
 Bunsen burner
 water bath
 infrared lamp
 wax annealer.
72
Some manufacturers
have come up with bite
wafers containing
copper and baseplate
wax containing
aluminium powder for
improving thermal
conductivity.
73
The poor thermal conductivity is an advantage
when carved wax surface is to be polished.
A brief exposure to a flame as it is passed quickly
over the surface achieves the necessary melting so
that the liquid can self-level driven by surface
tension.
74
MECHANICAL
PROPERTIES
Brittleness
Modulus of elasticity
Ductility
75
I. BRITTLENESS
Denture waxes need toughness since the wax
denture base may have to be removed from a
slightly undercut cast many times without
fracturing.
Inlay wax need to be brittle, so that the wax will
fracture rather than distort on removal from the
undercut cavity.
76
II. MODULUS OF ELASTICITY
:
• Low compared to other dental materials
• very important in hygroscopic expansion of casting
investment in which the wax pattern is subject to
stresses resulting from the expansion of the
investment during setting.
• Using waxes having different elastic moduli for
particular part of the wax pattern can minimize non-
uniform deformation of wax pattern.
77
III. DUCTILITY
Ductility increases as the temperature of a wax
specimen is increased .
waxes with lower melting temperatures have a
greater ductility of any given temperature than
those with higher melting temperatures.
78
FLOW / RHEOLOGICAL
PROPERTIES
• This property of flow results from the slippage of
molecules over each other.
• Flow of waxes is desirable as a part of the molding
process but becomes undesirable after the wax
pattern or impression has been made.
79
• The flow of wax of is dependant on
1. The temperature of wax
2. The force acting
3. The time the force is applied
80
• The higher the temperature, the greater the force and
the longer the time to which the wax is subjected to
those conditions, the greater the extent of flow.
81
RESIDUAL STRESS
• Distortion by relaxation of internal stresses
• Residual stress is typically the result of adapting wax
which is unevenly heated,
• but the relatively large thermal contraction of wax on
cooling may also induce stresses in the material.
82
BURN OUT
• The removal of wax from denture mould is a straight
forward procedure and easy.
• But the elimination of the wax from casting
investment mould is more complex.
• A combination of physical and chemical processes are
required to ensure that the mould space is clear.
• The wax should not leave any residues in the mould.
83
84
TYPES OF
DENTAL WAXES
85
TYPE OF WAX APPLICATION
Pattern wax Inlay wax
Resin wax
Casting wax
Baseplate wax
Impression wax Corrective wax
Biteplate wax
Soft impression wax
Disclosing wax
Processing wax Boxing wax
Beading wax
Sticky wax
Carving and blockout wax
Utility waxes
86
PATTERN WAXES
• used to form the carved pattern.
• used to form the general predetermined size and
contour of an artificial dental restoration
• to be constructed of a more durable material such as
cast gold alloys, cobalt chromium alloys.
87
IMPRESSION WAXES
•primarily used to take impression of the
edentulous region in the mouth.
•exhibit high flow at mouth temperature,
hence the name “mouth temperature waxes”.
88
PROCESSING WAXES
•primarily used as auxiliary aids in constructing
a variety of restoration and appliances either
in the clinic or in the laboratory.
89
INLAY WAX
90
INLAY WAX
• specialized dental wax that can be applied to dies to
form direct or indirect patterns for the lost wax
technique
• used for casting metals or hot pressing of ceramics.
91
• Supplied as Blue, green or purple rods or sticks
• about 5 to 7cms long and 6mm in diameter.
• Also available in the form of small pellets or cones in
jars
92
Classification
According to ADA Spec. No. 4
Type - 1, Medium wax used for forming direct
patterns in the mouth.
Type – II, soft wax used for indirect technique for
inlays and crowns.
93
IDEAL REQUIREMENTS OF INLAY
WAX
 Should uniformly soften without becoming
flaky or laminated.
 Should be smooth after molding and carving.
 Should be sufficiently plastic at temperature
slightly above mouth temperatures to permit
flow into all details of the cavity.
94
 Should harden sufficiently at mouth temperature.
 The colour should be such that it contrasts with
teeth and die material.
95
COMPOSITION
Paraffin 40-60% Base
Ceresin 10% modifier
Carnuaba wax 25%
Gum dummar 1%
Candelilla wax
Synthetic wax
colorants <1%
96
• Paraffin wax
main ingredient, which establishes the melting point.
• Ceresin
Partially replaces paraffin wax.
increases the toughness and makes it easy for
carving.
97
• Gum Dammar
improves smoothness
makes the inlay wax more resistant to cracking and
flaking
increases toughness of the wax
enhances luster of surface.
98
• Carnauba wax
reduces the flow at oral temperature
quite hard
high melting point
agreeable odour
gives glossiness to the wax surface.
99
• Candellila Wax
Usually replaces carnauba wax, but this has a low
melting range and it is not as hard as carnauba wax.
100
PROPERTIES OF
INLAY WAX
101
I . FLOW
According to ADA spec. no: 122
At 45 ºc → both type I and Type II should have flow
between 70-90%
At 37 ºc → Type I should not flow more than 1 %
At 30ºc → Type II should not flow more than 1%
102
The flow is restricted for Type I, since it is used to
fabricate direct wax pattern.
permits carving and removing of pattern from the
prepared cavity at oral temperature without
distortion.
Flow is reduced by adding carnauba wax or
beewax.
103
II. HOMOGENECITY
• The components of the wax should be evenly
distributed since it should have same properties
through out the solid
III. DUCTILITY
• moderate ductility
104
IV. BURNOUT
• The wax patterns are to be melted and vaporized
completely from the investment mold
• It is essential that no excessive residue occur.
• The specification limits non-volatile residues to a
maximum of 0.01% at 700oc
105
V. CONTACT ANGLE
• When the wax is melted it should wet the surface of
the material to which it is being added and spread
easily (low contact angle)
106
VI. WARPAGE OF WAX PATTERN
• Inlay pattern wax has a high co-efficient of expansion
• Tends to warp or distort when allowed to stand
unrestrained.
107
• This quality of wax pattern is related to the release of
residual stress developed in the pattern during the
process of formation .
• The release of internal stress and subsequent
warpage are associated with the storage temperature
and time.
108
VII. THERMAL PROPERTIES
• A decrease of 120 to 130C in temperature, from mouth
temperature to a room temperature of about 240C,
causes a 0.4% linear contraction of the wax.
109
FACTORS AFFECTING THERMAL
EXPANSION
 If the wax is allowed to cool under pressure its thermal
properties are changed.
When reheated, the linear coefficient of thermal
expansion is increased.
The temperature of the die and the method used to
apply pressure to wax as it solidifies also influences the
co-efficient of thermal expansion
110
 Carving should not cause chipping or flaking
 should be cohesive, not adhesive.
 should vaporize at temperatures (400 to 5000C)
without leaving any residue.
 should be dimensionally stable on temperature
changes (should not expand or shrink on melting or
solidifying)
 should not adhere to instruments
111
MANIPULATION OF INLAY
WAX
Direct technique
Indirect technique
112
113
114
115
CASTING WAX
oPatterns for metal frameworks of removable cast
partial dentures.
oCrown and bridge patterns
116
117
28 and 30
gauge (0.4
and 0.32mm)
thickness
round, half round
and half pear shaped
rod wires
Classification according to the Federal Specification No: U-
W-140
Class A – 28 gauge, pink
Class B - 30 gauge , green
Class C – readymade shapes, blue
118
–Max. flow at 35oc – 10%
–Min. flow at 38oc- 60%
–Readily adaptable at 40-45oc
–Vaporizes at 500º C without any residue
119
BASE PLATE WAX (MODELLING
WAX)
• Derives its name from its use on baseplate tray.
• ADA specification no: 24
120
121
Making occlusal rims
for registering the
vertical dimension,
arch form and plane
of occlusion.
Holding and
arranging artificial
teeth.
122
Extension of
impression tray
Spacer in custom
tray for complete
denture
123
To check articulating relations in the
mouth and to transfer them to the
articulator
•Classification:
ADA Sp. No. 24
Type 1 : Soft wax used for building contours and
veneers.
Type 2 : Hard wax patterns to be tried in the
mouth in temperate climate.
Type 3 : Extra hard wax, patterns to be tried in the
mouth in tropical climate.
124
BEADING AND BOXING WAX
• It is normally used to form a
matrix or mold around an
impression, so that it can be
poured with tissue side up.
• Such a technique minimizes
the amount of model
trimming and better controls
the thickness of cast base.
125
•Boxing wax
Long red strips
thickness 1/8 inch
width 1and ½ inches
length 12 inches
126
127
• As per the Federal Specification No U-W-138 the
properties are
It should be pliable at 210C.
It should retain its shape at 35oC
They should be readily adaptable to impression at
room temperature.
It should be slightly tacky and have sufficient
strength and toughness for ease of manipulation.
It should seal easily to plaster with hot spatula.
128
UTILITY WAX
Soft, adhesive and pliable wax
consists of beewax , petroleum and other soft waxes.
129
Used to modify the peripheral portion of
impression trays so that they more adequately
conform to the size and shape of dental arch.
Used to cover sharp brackets and wires in
orthodontic appliances.
130
STICKY WAX
131
USED FOR
 In denture repair
 Assembles components of fixed partial
denture and wrought partial dentures
Yellow beeswax, paraffin
and rosin
PROPERTIES
•Brittle at room temperature
•Thick consistency when heated
•Not more than 0.5% shrinkage from 43oc to
28oc
•Not more than 0.2% residue on burnout
132
BLOCK OUT WAX
• It is a type of processing wax.
• Used for filling the undercut area on the cast during
processing of the Cr-Co frame work.
133
DISCLOSING WAX
• Identify unequal pressure points in a denture
• Pressure indicator wax
134
LOW FUSING IMPRESSION WAX
Properties
Flow when subjected to controlled pressure
Indication
Reline and rebase dentures
135
Advantages
Boxing and separators not necessary while pouring the
cast
Disadvantages
Easily gets distorted
136
CORRECTIVE IMPRESSION WAX
137
Composition
• Paraffin
• Ceresin
• Beeswax
• Metal particles
 Korecta or Iowa wax
PROPERTIES INDICATIONS
•Soft wax -100% flow
at 37C
• Edentulous impressions
• Wax veneer over an
impression to contact and
register the details of soft
tissue
• Correcting small localized
imperfections in other
impressions 138
BITE REGISTRATION WAX
139
Composition
• Paraffin
• Ceresin
• Beeswax
• Alumina or copper particles
Eg: aluwax
ALUWAX
140
• Contains powdered
aluminum
• Increase the integrity of
the compound
• Provide the heat retention
properties needed for
efficient modeling.
SUMMARY
Dental waxes are available in different forms, shapes,
sizes and compositions depending on the function it
has to perform.
The waxes used in dentistry normally consist of two
or more components which may be natural or
synthetic waxes, resins, oils, fats and pigments.
141
Blending is carried out to produce a material with the
required properties for specific applications.
Waxes are thermoplastic materials which are
normally solids at room temperature but melt without
decomposition to form mobile liquids.
142
REFERENCES
• Anusavice KJ: Phillips science of dental materials,
2012,11th edition, Elsevier
• O’ Brien WJ: dental materials and their selection, 9th
edition, 2008, Quintessence publishers
• Powers JM, Wataha JC: Dental materials: properties
and manipulation,2008, 9th edition, Elseiver, St Louis
• Mahalakshmi S. Materials used in dentistry, 2013,
Wolter Kluwer,Haryana
143
• Bhat VS, Nandish BT. Science of dental materials:
clinical applications,2nd edition, CBS publishers
• McCabe JF, Walls AWG.Applied dental materials ,9th
edition, Blackwell munkgaard
• Craig RC, Powers JM. Restoraive dental materials, 11th
edition, 2005, elseiver, St louis
144
• Ito M, Yamagishi T, Oshida Y, Munoz CA. Effect of
selected physical propertiesof waxes on investments
and casting shrinkage. J Prosthet Dent
1996;75(2):211-6
• Kotisiomiti E, McCabe JF. Stability of dental waxes
following repeated heatings. J Oral
Rehabil1995;22(2);135-43
• Kotisiomiti E, McCabe JF. Experimiental wax mixture
for dental use. J Oral Rehabil 1997;24(7):517-21
• Iglesias A, Powers JM, Pierpont HD. Accuracy of wax,
autopolymerized resin pattern materials. J
Prosthodont 1996; 5(3);201-5
145
JOURNAL REFERENCES
• Ito M, Kuriowa A, Nagasawa S, Yoshida T, Yagasaki H.
Effect of wax melting range and investment liquid
concentration on the accuracy. J Prosthet Dent
2002;87:57-61
• Craig RG, Eick JD, Peyton FA. Flow of binary and
teritiary mixture of waxes. J Den Research
1966;45(2):397-403
• Zeltzer C, Lewinsten I, Grayower R. Fit of crown wax
patterns after removal from die. J Prosthet Dent
1985;53(3):344-6
146
147

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Dental waxes ppt

  • 2. CONTENTS 1. Introduction 2. Historical background 3. Classification 4. Individual component waxes 5. General composition of dental waxes 6. Ideal requisites of dental waxes 7. Properties of waxes 8. Different types of dental waxes 9. Summary 10. References 2
  • 3. INTRODUCTION • Variety of natural waxes and resins have been used in dentistry for specific and well defined applications • Few procedures in Prosthodontics can be completed without the use of wax in one of its many forms. • It is obvious that the tasks these waxes perform and their properties vary greatly. 3
  • 4. A low-molecular-weight hydrocarbons or ester of fatty acids derived from natural or synthetic components, such as petroleum derivatives, that soften to a plastic state at a relatively low temperature. 4
  • 5. Natural and synthetic waxes Gums Fats Fatty acids Oils Natural and synthetic resins Pigments of different types. 5
  • 6. DEFINITION Dental waxes can be defined as a thermoplastic molding material that is solid at room temperature and when subjected to moderate temperatures becomes a low viscosity fluid. Waxes are hydrocarbons or alcohols or esters of fatty acids. 6
  • 7. •Color coding: blue, green, yellow, red and ivory •These colors are useful to provide a suitable contrast against a die that is an accurate replica of a prepared tooth or arch form. 7
  • 8. HISTORICAL BACKGROUND • Wax has been a valuable commodity for over 2000 years. • In ancient times beeswax was used ,which was derived from secretions that bees use to build honeycombs. 8
  • 9. • First inlay in dentistry is credited to JOHN MURPHY of London who was fabricating porcelain inlay in 1855. • First cast inlay is attributed to PHILBROOK in 1897. • TAGGART in 1907 introduced lost wax technique 9
  • 11. CLINICAL LABORATORY  Bite registration wax  Disclosing wax  Type I inlay wax  Boxing wax  Beading wax  Baseplate wax  Sticky wax  Utility wax  Type II Inlay wax 11
  • 12. 12 Based on components of dental waxes Natural waxes Synthetic waxes Wax additives
  • 13. •Based on origin of waxes can be classified as – Natural : mineral origin plant origin insect origin animal origin – Synthetic waxes 13
  • 14. TYPE OF WAX APPLICATION Pattern wax Inlay wax Resin wax Casting wax Baseplate wax Impression wax Corrective wax Biteplate wax Soft impression wax Disclosing wax Processing wax Boxing wax Beading wax Sticky wax Carding and blockout wax Utility waxes 14 Based on uses
  • 15. •Based on chemical composition Waxes containing organic compounds Hydrocarbons Esters Waxes containing free alcohols and acids 15
  • 17. 17
  • 18. • Coloring agents are added for contrast of wax patterns against tooth, die, and model surfaces. • Some formulations contain a compatible filler to control expansion and shrinkage of the wax product. 18
  • 19. 19 COMPONENTS OF DENTAL WAXES NATURAL WAXES SYNTHETIC WAXES ADDITIVES  MINERAL  PLANT  INSECT  ANIMAL  POLYETHYLENE  POLYOXYETHELENE  HYDROGENATED  OILS  COLORS  FATS  NATURAL RESINS  SYNTHETIC RESINS
  • 20. 20 NATURAL SYNTHETIC WAXES ADDITIVES MINERALS Paraffin Microcrystalline Barnsdahl Ozokerite Ceresin Montan Acrawax C Aerosol OT Castor wax Flexowax C Epolene N-10 Albacer Aldo 33 Durawax 1032 Fats • Stearic acid • Glyceryl tristeartae Oils • Turpentine • color PLANTS Carnuaba Ouricury Candelilla Japan wax Coco butter Natural resins Rosin Copal Dammar Sandarac Mastic Shellac Kauri INSECTS ANIMALS Beeswax spemaceti Synthetic resins Elvax Polyethylene
  • 22. i. Paraffin wax: Major component of most dental waxes. Obtained from the high boiling point fractions of petroleum. The presence of oil in the wax however lowers the melting temperature. 22 MINERAL ORIGIN
  • 23. paraffin waxes used in dentistry are refined waxes and have less than 5% oil. They melt at in the range of 400C and 710C. Melting temperature increases with increasing molecular weight. 23
  • 24. Paraffin waxes produced by current refining procedures that can crystallize in the form of plates, needles and small crystals  but are usually of plate type. Many hydrocarbon waxes undergo crystalline changes on cooling  transition from needles to plates occurs about 50 to 80C below their melting temperature 24
  • 25.  Paraffin wax flakes easily when trimmed and does not achieve a smooth and glossy surface.  Hence other waxes and resins have to be added to modify paraffin and improve properties of dental waxes. 25
  • 26. Are similar to paraffin waxes except they are obtained from the heavier oil fractions in the petroleum industry. They consist of mixture of microcrystalline hydrocarbons, which is purified branched chain of hydrocarbons, saturated monocyclic and polycyclic compounds and normal alkanes. They have higher melting range (600C to 910C) 26 ii. Microcrystalline wax:
  • 27. crystallize in small plates tougher more flexible than paraffin waxes. They are darker in color and have higher viscosity. They have an affinity for oil hardness and tackiness may be altered by adding oil. 27
  • 28. Microcrystalline waxes have less volumetric change during solidification than paraffin waxes. These waxes are added to paraffin wax to To raise melting point and hardness Make material less brittle They reduces stresses that occur on cooling 28
  • 29. It is an earth wax found near petroleum deposits in Central Europe and the Western United States. It is composed of straight and branched chain hydrocarbons, along with few closed-chain hydrocarbons. 29 iii. Ozokerite
  • 30. Greatest affinity for oils, and in quantities of 5% to 15% greatly improves the properties of paraffin wax. Unpleasant odour Melting point 65o C 30
  • 31. White wax extracted from ozokerite Composed of straight and branched chain hydrocarbons. higher molecular weight and greater hardness than hydrocarbon waxes distilled from crude products. used to increase the melting range of paraffin waxes. 31 iv. Ceresin:
  • 32. Hard wax obtained by solvent extraction of certain types of lignite or brown coal. Although they are mineral waxes, their composition and properties are similar to those of the plant waxes. 32 v. Montan wax
  • 33. Composed of long chain esters. Melting range- 720 C- 920 C Hard, brittle and lustrous they blend well with other waxes, and therefore are often substituted for plant waxes to improve the hardness and melting range of paraffin waxes. 33
  • 34. PLANT ORIGIN i. Carnauba wax and Ouricury wax: Both composed of straight chain esters, alcohols and hydrocarbons. Characterized by high hardness, brittleness and high melting temperatures 34
  • 35. Both possess the outstanding quality of increasing the melting range and hardness of paraffin waxes. Adding 6% of carnauba wax to paraffin wax with a melting range of 200C, increases the melting range to 460C. 35
  • 36. Consists of 40 to 60% paraffin hydrocarbons containing 29 to 33 carbon atoms, accompanied by free alcohols, acids esters and lactones. Melting range is lower than carnauba wax( 63- 700c) Like carnauba and ouricury wax, they harden paraffin waxes but are not so effective for increasing melting range Craig et al. Properties of natural waxes used in dentistry. J.Dent. Res.Nov- Dec 1965 36 ii. Candelilla wax
  • 37. Chiefly fat Obtained from berries of certain sumac Glycerides of palmitic acid and stearic acid Tough, malleable and sticky Melting point: 51oc Mixed with paraffin to improve tackiness and emulsifying ability Craig et al. Properties of natural waxes used in dentistry. J.Dent. Res.Nov-Dec 1965 37 iii. Japan wax (Sumac wax)
  • 38. Chiefly fat Composed of glycerides of stearic acid, palmitic, oleic, lauric, lower fatty acids Brittle at room temperature 38 iv. Coco butter
  • 39. • Used to protect against dehydration of soft tissues • To protect GIC from moisture or dehydration during their setting. 39
  • 40. INSECT ORIGIN Obtained from honey combs desirable flow properties Is a brittle material at room temperature becomes plastic when heated. Craig et al. Properties of natural waxes used in dentistry. J.Dent. Res.Nov-Dec 1965 40 Beeswax
  • 41.  Melting temp range : 63-70oc  Mixture of saturated and unsaturated hydrocarbons, organic acids and myricyl palmitate  Main component of sticky wax 41
  • 42. ANIMAL ORIGIN Obtained from the sperm whale  Mainly esters  Not used extensively in dentistry  Some times used for coating the dental floss 42 Spermaceti wax
  • 44. Synthetic waxes are produced by  combination of various chemicals in the laboratory  chemical action on natural waxes Such as chlorine in the preparation of halogenated waxes and hydrogen in the manufacture of hydrogenated waxes 44
  • 45. • Differ from natural waxes in certain characteristics high degree of refinement, in contrast with the contamination that is common in natural waxes. 45
  • 46. Synthetic waxes include • Polyethylene waxes • polyoxyethylene glycol waxes • Halogenated hydrocarbon waxes • Wax esters from reaction of fatty alcohol and acids 46
  • 48. I. GUMS Viscous, amorphous exudates that harden on exposure to air largely carbohydrates. when they are mixed with water, they either dissolve or form sticky, viscous liquids. 48
  • 49. • GUM ARABIC and TRAGACANTH are two natural gums (do not resemble waxes in either their properties or composition) 49
  • 50. II. FATS Esters of various fatty acids Tasteless, odorless and colorless (pure form) Increase the melting range and hardness of the compounded wax Craig et al. Properties of natural waxes used in dentistry. J.Dent. Res.Nov-Dec 1965 50
  • 51. Hydrocarbon oils may be used to soften mixtures of waxes Small quantities of silicon oils may be added to improve the ease of polishing with waxes. 51
  • 52. III. RESINS 52 NATURAL RESINS SYNTHETIC RESINS Dammar polyethylene Rosin vinyl resin Sandarac polystyrene Shellac Copal
  • 53. • Complex, amorphous mixtures of organic substances • Characterized by specific physical behavior rather than by any definite chemical composition. • Many species of trees and other plants produce exudates of natural resins such as dammar, rosin or sandarac , • Except shellac which is produced by insects. 53
  • 54. • Most of the natural resins like dammar blend with waxes to get the desirable properties for dental applications. • Synthetic resins, such as polyethylene and vinyl resins of various types may be added to paraffin waxes to improve their toughness, film forming characteristics and melting ranges. 54
  • 56. COMPONENT INGREDIENT EXAMPLE Base Paraffin Modifiers High molecular weight hydrocarbon or ester Beeswax Carnauba wax Candelilla wax Ceresin colorants 56
  • 57. IDEAL REQUISITES OF DENTAL WAXES 57  Should flow easily  Should be dimensionally stable  Should have a pleasant colour and should possess a colour contrast to help during carving and proper finishing of margins.  When softened, the wax should be uniform
  • 58. 58  Should be tough and rigid at room temperature and not brittle.  Should have a low softening temperature  It should have a low coefficient of thermal expansion  Should reproduce finer
  • 59. 59  It should not leave any residues when wax is eliminated from the mould  Should be cheap and easy to use.  Should be sufficiently strong to resist abrasion and distortion.
  • 61. Thermal properties Mechanical properties Flow/ rheological properties Residual stress Burnout 61
  • 62. THERMAL PROPERTIES Melting point/ range Softening temperature Thermal conductivity The coefficient of thermal expansion 62
  • 63. I. MELTING RANGE 63 • Because waxes are mixtures of different components, they donot have a single temperature • Donot have a melting points • Rather they have “ MELTING RANGE”
  • 64. • At a low end of the range, some but not all components melt, which causes the wax, still solid , to flow much more. • As the temperature ↑ ses through the melting range, more of the components melt and the wax flow severely & eventually all components become liquid. • Significance: mixing of waxes can change their melting range. 64
  • 65. II. SOFTENING TEMPERATURE Waxes exhibit solid-solid transition temperature , which is closely related to the softening temperature. 65
  • 66. 66 Typical thermograph of wax indicating solid- solid transition (a) and melting point (b)
  • 67. • This peak is indicative of a solid-solid transition involving a change in the crystal structure of the wax. • The change in the crystal structure is accompanied by a change in the in the mechanical properties and the wax is converted from a relatively brittle solid to a much softer, moldable material. • For this reason the solid-solid temperature is referred to as softening temperature. 67
  • 68.  Clinical significance:  For many applications of waxes, the softening temperature should be just above the mouth temperature. the material may be introduced into the mouth in a moldable state but will become relatively rigid at mouth temperature. 68
  • 69. III. CO-EFFICIENT OF THERMAL EXPANSION • Major factor affecting the accuracy. • Waxes expand when subjected to a rise in temperature and contract as the temperature is decreased . 69
  • 70. • Dental waxes and their components have the largest co-efficient of thermal expansion of any material used in restorative dentistry. • Very large coefficient of thermal expansion –150- 400ppm /0 C • Due to this large COTE, contraction of wax patterns take place by about 0.3% to 0.8% when cooled from 370c to room temperature 70
  • 71. IV. THERMAL CONDUCTIVITY Waxes are poor conductors of heat Thus temperature should be maintained above the solid-solid transition temperature for long enough to allow thorough softening to occur throughout the material before molding is attempted The practical implication is heat slowly and uniformly. 71
  • 72. The different methods of softening wax  Bunsen burner  water bath  infrared lamp  wax annealer. 72
  • 73. Some manufacturers have come up with bite wafers containing copper and baseplate wax containing aluminium powder for improving thermal conductivity. 73
  • 74. The poor thermal conductivity is an advantage when carved wax surface is to be polished. A brief exposure to a flame as it is passed quickly over the surface achieves the necessary melting so that the liquid can self-level driven by surface tension. 74
  • 76. I. BRITTLENESS Denture waxes need toughness since the wax denture base may have to be removed from a slightly undercut cast many times without fracturing. Inlay wax need to be brittle, so that the wax will fracture rather than distort on removal from the undercut cavity. 76
  • 77. II. MODULUS OF ELASTICITY : • Low compared to other dental materials • very important in hygroscopic expansion of casting investment in which the wax pattern is subject to stresses resulting from the expansion of the investment during setting. • Using waxes having different elastic moduli for particular part of the wax pattern can minimize non- uniform deformation of wax pattern. 77
  • 78. III. DUCTILITY Ductility increases as the temperature of a wax specimen is increased . waxes with lower melting temperatures have a greater ductility of any given temperature than those with higher melting temperatures. 78
  • 79. FLOW / RHEOLOGICAL PROPERTIES • This property of flow results from the slippage of molecules over each other. • Flow of waxes is desirable as a part of the molding process but becomes undesirable after the wax pattern or impression has been made. 79
  • 80. • The flow of wax of is dependant on 1. The temperature of wax 2. The force acting 3. The time the force is applied 80
  • 81. • The higher the temperature, the greater the force and the longer the time to which the wax is subjected to those conditions, the greater the extent of flow. 81
  • 82. RESIDUAL STRESS • Distortion by relaxation of internal stresses • Residual stress is typically the result of adapting wax which is unevenly heated, • but the relatively large thermal contraction of wax on cooling may also induce stresses in the material. 82
  • 83. BURN OUT • The removal of wax from denture mould is a straight forward procedure and easy. • But the elimination of the wax from casting investment mould is more complex. • A combination of physical and chemical processes are required to ensure that the mould space is clear. • The wax should not leave any residues in the mould. 83
  • 84. 84
  • 86. TYPE OF WAX APPLICATION Pattern wax Inlay wax Resin wax Casting wax Baseplate wax Impression wax Corrective wax Biteplate wax Soft impression wax Disclosing wax Processing wax Boxing wax Beading wax Sticky wax Carving and blockout wax Utility waxes 86
  • 87. PATTERN WAXES • used to form the carved pattern. • used to form the general predetermined size and contour of an artificial dental restoration • to be constructed of a more durable material such as cast gold alloys, cobalt chromium alloys. 87
  • 88. IMPRESSION WAXES •primarily used to take impression of the edentulous region in the mouth. •exhibit high flow at mouth temperature, hence the name “mouth temperature waxes”. 88
  • 89. PROCESSING WAXES •primarily used as auxiliary aids in constructing a variety of restoration and appliances either in the clinic or in the laboratory. 89
  • 91. INLAY WAX • specialized dental wax that can be applied to dies to form direct or indirect patterns for the lost wax technique • used for casting metals or hot pressing of ceramics. 91
  • 92. • Supplied as Blue, green or purple rods or sticks • about 5 to 7cms long and 6mm in diameter. • Also available in the form of small pellets or cones in jars 92
  • 93. Classification According to ADA Spec. No. 4 Type - 1, Medium wax used for forming direct patterns in the mouth. Type – II, soft wax used for indirect technique for inlays and crowns. 93
  • 94. IDEAL REQUIREMENTS OF INLAY WAX  Should uniformly soften without becoming flaky or laminated.  Should be smooth after molding and carving.  Should be sufficiently plastic at temperature slightly above mouth temperatures to permit flow into all details of the cavity. 94
  • 95.  Should harden sufficiently at mouth temperature.  The colour should be such that it contrasts with teeth and die material. 95
  • 96. COMPOSITION Paraffin 40-60% Base Ceresin 10% modifier Carnuaba wax 25% Gum dummar 1% Candelilla wax Synthetic wax colorants <1% 96
  • 97. • Paraffin wax main ingredient, which establishes the melting point. • Ceresin Partially replaces paraffin wax. increases the toughness and makes it easy for carving. 97
  • 98. • Gum Dammar improves smoothness makes the inlay wax more resistant to cracking and flaking increases toughness of the wax enhances luster of surface. 98
  • 99. • Carnauba wax reduces the flow at oral temperature quite hard high melting point agreeable odour gives glossiness to the wax surface. 99
  • 100. • Candellila Wax Usually replaces carnauba wax, but this has a low melting range and it is not as hard as carnauba wax. 100
  • 102. I . FLOW According to ADA spec. no: 122 At 45 ºc → both type I and Type II should have flow between 70-90% At 37 ºc → Type I should not flow more than 1 % At 30ºc → Type II should not flow more than 1% 102
  • 103. The flow is restricted for Type I, since it is used to fabricate direct wax pattern. permits carving and removing of pattern from the prepared cavity at oral temperature without distortion. Flow is reduced by adding carnauba wax or beewax. 103
  • 104. II. HOMOGENECITY • The components of the wax should be evenly distributed since it should have same properties through out the solid III. DUCTILITY • moderate ductility 104
  • 105. IV. BURNOUT • The wax patterns are to be melted and vaporized completely from the investment mold • It is essential that no excessive residue occur. • The specification limits non-volatile residues to a maximum of 0.01% at 700oc 105
  • 106. V. CONTACT ANGLE • When the wax is melted it should wet the surface of the material to which it is being added and spread easily (low contact angle) 106
  • 107. VI. WARPAGE OF WAX PATTERN • Inlay pattern wax has a high co-efficient of expansion • Tends to warp or distort when allowed to stand unrestrained. 107
  • 108. • This quality of wax pattern is related to the release of residual stress developed in the pattern during the process of formation . • The release of internal stress and subsequent warpage are associated with the storage temperature and time. 108
  • 109. VII. THERMAL PROPERTIES • A decrease of 120 to 130C in temperature, from mouth temperature to a room temperature of about 240C, causes a 0.4% linear contraction of the wax. 109
  • 110. FACTORS AFFECTING THERMAL EXPANSION  If the wax is allowed to cool under pressure its thermal properties are changed. When reheated, the linear coefficient of thermal expansion is increased. The temperature of the die and the method used to apply pressure to wax as it solidifies also influences the co-efficient of thermal expansion 110
  • 111.  Carving should not cause chipping or flaking  should be cohesive, not adhesive.  should vaporize at temperatures (400 to 5000C) without leaving any residue.  should be dimensionally stable on temperature changes (should not expand or shrink on melting or solidifying)  should not adhere to instruments 111
  • 112. MANIPULATION OF INLAY WAX Direct technique Indirect technique 112
  • 113. 113
  • 114. 114
  • 115. 115
  • 116. CASTING WAX oPatterns for metal frameworks of removable cast partial dentures. oCrown and bridge patterns 116
  • 117. 117 28 and 30 gauge (0.4 and 0.32mm) thickness round, half round and half pear shaped rod wires
  • 118. Classification according to the Federal Specification No: U- W-140 Class A – 28 gauge, pink Class B - 30 gauge , green Class C – readymade shapes, blue 118
  • 119. –Max. flow at 35oc – 10% –Min. flow at 38oc- 60% –Readily adaptable at 40-45oc –Vaporizes at 500º C without any residue 119
  • 120. BASE PLATE WAX (MODELLING WAX) • Derives its name from its use on baseplate tray. • ADA specification no: 24 120
  • 121. 121 Making occlusal rims for registering the vertical dimension, arch form and plane of occlusion. Holding and arranging artificial teeth.
  • 122. 122 Extension of impression tray Spacer in custom tray for complete denture
  • 123. 123 To check articulating relations in the mouth and to transfer them to the articulator
  • 124. •Classification: ADA Sp. No. 24 Type 1 : Soft wax used for building contours and veneers. Type 2 : Hard wax patterns to be tried in the mouth in temperate climate. Type 3 : Extra hard wax, patterns to be tried in the mouth in tropical climate. 124
  • 125. BEADING AND BOXING WAX • It is normally used to form a matrix or mold around an impression, so that it can be poured with tissue side up. • Such a technique minimizes the amount of model trimming and better controls the thickness of cast base. 125
  • 126. •Boxing wax Long red strips thickness 1/8 inch width 1and ½ inches length 12 inches 126
  • 127. 127
  • 128. • As per the Federal Specification No U-W-138 the properties are It should be pliable at 210C. It should retain its shape at 35oC They should be readily adaptable to impression at room temperature. It should be slightly tacky and have sufficient strength and toughness for ease of manipulation. It should seal easily to plaster with hot spatula. 128
  • 129. UTILITY WAX Soft, adhesive and pliable wax consists of beewax , petroleum and other soft waxes. 129
  • 130. Used to modify the peripheral portion of impression trays so that they more adequately conform to the size and shape of dental arch. Used to cover sharp brackets and wires in orthodontic appliances. 130
  • 131. STICKY WAX 131 USED FOR  In denture repair  Assembles components of fixed partial denture and wrought partial dentures Yellow beeswax, paraffin and rosin
  • 132. PROPERTIES •Brittle at room temperature •Thick consistency when heated •Not more than 0.5% shrinkage from 43oc to 28oc •Not more than 0.2% residue on burnout 132
  • 133. BLOCK OUT WAX • It is a type of processing wax. • Used for filling the undercut area on the cast during processing of the Cr-Co frame work. 133
  • 134. DISCLOSING WAX • Identify unequal pressure points in a denture • Pressure indicator wax 134
  • 135. LOW FUSING IMPRESSION WAX Properties Flow when subjected to controlled pressure Indication Reline and rebase dentures 135
  • 136. Advantages Boxing and separators not necessary while pouring the cast Disadvantages Easily gets distorted 136
  • 137. CORRECTIVE IMPRESSION WAX 137 Composition • Paraffin • Ceresin • Beeswax • Metal particles  Korecta or Iowa wax
  • 138. PROPERTIES INDICATIONS •Soft wax -100% flow at 37C • Edentulous impressions • Wax veneer over an impression to contact and register the details of soft tissue • Correcting small localized imperfections in other impressions 138
  • 139. BITE REGISTRATION WAX 139 Composition • Paraffin • Ceresin • Beeswax • Alumina or copper particles Eg: aluwax
  • 140. ALUWAX 140 • Contains powdered aluminum • Increase the integrity of the compound • Provide the heat retention properties needed for efficient modeling.
  • 141. SUMMARY Dental waxes are available in different forms, shapes, sizes and compositions depending on the function it has to perform. The waxes used in dentistry normally consist of two or more components which may be natural or synthetic waxes, resins, oils, fats and pigments. 141
  • 142. Blending is carried out to produce a material with the required properties for specific applications. Waxes are thermoplastic materials which are normally solids at room temperature but melt without decomposition to form mobile liquids. 142
  • 143. REFERENCES • Anusavice KJ: Phillips science of dental materials, 2012,11th edition, Elsevier • O’ Brien WJ: dental materials and their selection, 9th edition, 2008, Quintessence publishers • Powers JM, Wataha JC: Dental materials: properties and manipulation,2008, 9th edition, Elseiver, St Louis • Mahalakshmi S. Materials used in dentistry, 2013, Wolter Kluwer,Haryana 143
  • 144. • Bhat VS, Nandish BT. Science of dental materials: clinical applications,2nd edition, CBS publishers • McCabe JF, Walls AWG.Applied dental materials ,9th edition, Blackwell munkgaard • Craig RC, Powers JM. Restoraive dental materials, 11th edition, 2005, elseiver, St louis 144
  • 145. • Ito M, Yamagishi T, Oshida Y, Munoz CA. Effect of selected physical propertiesof waxes on investments and casting shrinkage. J Prosthet Dent 1996;75(2):211-6 • Kotisiomiti E, McCabe JF. Stability of dental waxes following repeated heatings. J Oral Rehabil1995;22(2);135-43 • Kotisiomiti E, McCabe JF. Experimiental wax mixture for dental use. J Oral Rehabil 1997;24(7):517-21 • Iglesias A, Powers JM, Pierpont HD. Accuracy of wax, autopolymerized resin pattern materials. J Prosthodont 1996; 5(3);201-5 145 JOURNAL REFERENCES
  • 146. • Ito M, Kuriowa A, Nagasawa S, Yoshida T, Yagasaki H. Effect of wax melting range and investment liquid concentration on the accuracy. J Prosthet Dent 2002;87:57-61 • Craig RG, Eick JD, Peyton FA. Flow of binary and teritiary mixture of waxes. J Den Research 1966;45(2):397-403 • Zeltzer C, Lewinsten I, Grayower R. Fit of crown wax patterns after removal from die. J Prosthet Dent 1985;53(3):344-6 146
  • 147. 147

Editor's Notes

  1. Waxes are used in many aspects of dentistry in the clinics and in the laboratory Although it is not the final restoration, waxes are often imp in the success and fabrication of final metal or ceramic restoration
  2. Composed of the foll: The particular working characteristics of each wax are achieved by blending the appropriate natural and synthetic waxes and resins and other additives in the right proportions.
  3. The dental waxes may be composed of natural waxes and synthetic waxes, gums, fats, fatty acids, oils. Natural waxes are derived from mineral, vegetable, and animal origins. Synthetic waxes are chemically synthesized from natural wax molecules and are typically composed of hydrogen, carbon, oxygen, and chlorine.
  4. Added to many waxes because of its desirable flow properties
  5. Although they differ chemically from natural waxes, they have certain physical properties, such as melting temperature and hardness, which are similar to those of natural waxes.
  6. Differ from natural waxes in certain characteristics because of their high degree of refinement, in contrast with the contamination that is common in natural waxes.
  7. Polyethylene polymers are waxes having molecular weight of 2000 to 4000 and melting range of 100oC- 105oC. These waxes possess properties similar to higher molecular weight paraffin waxes obtained from petroleum. Polyoxyethylene waxes are polymers of ethylene glycols and have melting temperature from 370C to 630C. They have limited compatibility with other waxes but do function as plasticizers and tend to toughen films of wax.
  8. 1. Most gums are complicated substances. Many are mixtures containing largely carbohydrates
  9. Waxes used in dentistry may be composed of natural and synthetic waxes, gums fats, oils, natural and synthetic resins and pigments of various types. Each type of dental wax is manufactured by blending of appropriate quantities of the ingredients to achieve the particular characteristics needed for the intended use. The average molecular weight of a wax blend is about 400- 4000, which is very low when compared to acrylic polymers
  10. Waxes are generally characterized by their thermal properties such as Melting point/ range Softening temperature Thermal conductivity The coefficient of thermal expansion
  11. This peak is indicative of a solid-solid transition involving a change in the crystal structure of the wax. The change in the crystal structure is accompanied by a change in the in the mechanical properties and the wax is converted from a relatively brittle solid to a much softer, moldable material. For this reason the solid-solid temperature is referred to as softening temperature.
  12. This peak is indicative of a solid-solid transition involving a change in the crystal structure of the wax. The change in the crystal structure is accompanied by a change in the in the mechanical properties and the wax is converted from a relatively brittle solid to a much softer, moldable material. For this reason the solid-solid temperature is referred to as softening temperature.
  13. The mechanical properties of waxes are relatively poor than those of other dental materials.
  14. Clinical significance: Ideally, the materials should exhibit considerable flow at the molding temperature but should have little or no flow at mouth temperature or room temperature so that they are not easily distorted. By varying the different components, the properties of waxes can be fine-tuned.
  15. Carnauba wax: When this is combined with paraffin wax, it reduces the flow at oral temperature. It is quite hard and has a high melting point. It has agreeable odour and gives glossiness to the wax surface. Candellila Wax This usually replaces carnauba wax, but this has a low melting range and it is not as hard as carnauba wax.
  16. The accuracy and ultimate usefulness of the resulting gold casting depend largely on the accuracy and fine details of the wax pattern.
  17. 1. Knowing the amount of wax expansion or contraction allows one to judge the compensation necessary to produce an accurate casting.
  18. Composition : is similar to inlay wax Ready made shapes round, half round and half pear shaped rod wires are approximately 10cm in length The different shapes resemble lingual bars, clasps, connectors and skeletal framework for edentulous areas.